Synthesis, Spectral Characterization, Crystal Structure and Thermal Behavior of Tert-butyl 2,2-bis(2,4-dinitrophenyl)ethanoate
Data(s) |
2012
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Resumo |
Tert-butyl 2,2-bis(2,4-dinitrophenyl)ethanoate was prepared from the ethanolic solution of 1-chloro-2,4-dinitrobenzene, tert-butyl 3-oxobutanoate and triethylamine. Acetyl group in tert-butyl 3-oxobutanoate has cleaved off during the formation of the title molecule. UV-VIS, IR, 1H NMR, 13C NMR, Proton-Proton COSY data and single crystal XRD results support the proposed structure. Flammability test, impact sensitivity test and TG/DTA studies at different heating rates on the synthesized molecule imply that it is an insensitive high energy density material. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/45480/1/jou_che_cry_42-11_1098_2012.pdf Kalaivani, D and Malarvizhi, R and Nethaji, M (2012) Synthesis, Spectral Characterization, Crystal Structure and Thermal Behavior of Tert-butyl 2,2-bis(2,4-dinitrophenyl)ethanoate. In: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 42 (11). pp. 1098-1104. |
Publicador |
Springer Science+Business Media |
Relação |
http://dx.doi.org/10.1007/s10870-012-0363-0 http://eprints.iisc.ernet.in/45480/ |
Palavras-Chave | #Inorganic & Physical Chemistry |
Tipo |
Journal Article PeerReviewed |