Novel double insertion of carbon disulfide into two Ru-H bonds of [(dppm)(2)Ru(H)(2)] (dppm = Ph2PCH2PPh2): Synthesis and crystal structure of a methanedithiolate complex
| Data(s) |
10/02/2003
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|---|---|
| Resumo |
Addition of excess carbon disulfide to cis/trans-[(dPPM)(2)Ru(H)(2)] results in the methanedithiolate complex [(dppm)(2)Ru(eta(2)-S2CH2)] 4 via the intermediacy of cis-[(dppm)(2)Ru(H)(SC(S)H)] 2. The X-ray crystal structure of this species has been determined. |
| Formato |
application/pdf application/pdf other |
| Identificador |
http://eprints.iisc.ernet.in/40150/1/Novel_Double_Insertion.pdf http://eprints.iisc.ernet.in/40150/2/Supporting_Information.pdf http://eprints.iisc.ernet.in/40150/7/ic0260320-2_s1.cif Gandhi, Thirumanavelan and Nethaji, Munirathinam and Jagirdar, Balaji R (2003) Novel double insertion of carbon disulfide into two Ru-H bonds of [(dppm)(2)Ru(H)(2)] (dppm = Ph2PCH2PPh2): Synthesis and crystal structure of a methanedithiolate complex. In: Inorganic Chemistry, 42 (3). 667-669 . |
| Publicador |
American Chemical Society |
| Relação |
http://pubs.acs.org/doi/abs/10.1021/ic0260320 http://eprints.iisc.ernet.in/40150/ |
| Palavras-Chave | #Inorganic & Physical Chemistry |
| Tipo |
Journal Article PeerReviewed |
