Acylation of Grignard reagents mediated by N-methylpyrrolidone: A remarkable selectivity for the synthesis of ketones
| Data(s) |
2011
|
|---|---|
| Resumo |
An efficient user-friendly method of acylation of Grignard reagents to selectively synthesize ketones is presented, which is assisted by simple amides such as NMP, or DMF. The present chemoselective method tolerates a variety of functional groups such as ketone, ester, nitrile and other functional groups. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/39746/1/Acylation_of_Grignard.pdf Gowda, Maravanhalli Sidde and Pande, Sushanth Sudhir and Ramakrishna, Ramesha Andagar and Prabhu, Kandikere Ramaiah (2011) Acylation of Grignard reagents mediated by N-methylpyrrolidone: A remarkable selectivity for the synthesis of ketones. In: Organic and Biomolecular Chemistry, 9 (15). pp. 5365-5368. |
| Publicador |
Royal Society of Chemistry |
| Relação |
http://pubs.rsc.org/en/Content/ArticleLanding/2011/OB/C1OB05780D http://eprints.iisc.ernet.in/39746/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
