The chemistry of a non-natural product: Troger's base
Data(s) |
10/02/1995
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Resumo |
Troger's base was the first amine to be resolved where the chirality was solely due to very high inversion barrier around nitrogen atom(s). Though the molecule was known over a century, work done during the past one decade has shown that Troger's base and its analogues could be used as chiral solvating agents, DNA-binding ligands and for the construction of biomimetic molecular receptors and clathrate hosts, Asymmetric synthesis of Troger's base analogues has also been achieved recently, Because of the rigid, 'V'-shaped chiral nature of this molecule, there is a growing interest for use of this unit in the design of potential host systems, This review article focuses on the chemistry of Troger's base along with the possible future utilities. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/37956/1/Chemist.pdf Bag, Braja Gopal (1995) The chemistry of a non-natural product: Troger's base. In: Current Science (Bangalore), 68 (3). pp. 279-288. |
Publicador |
Indian Academy of Sciences |
Relação |
http://www.ias.ac.in/j_archive/currsci/68/vol68contents.html http://eprints.iisc.ernet.in/37956/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |