Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels


Autoria(s): Selvakumar, Natesan; Janaki, Seenivasaga N; Pramod, Kakumanu; Rao, Subba GSR
Data(s)

07/04/1995

Resumo

The first stereoselective total synthesis of the novel sesquiterpenes 1 and 2 is described. The preparation of the key intermediate 27 involved a rearrangement of a bicyclo[3.2.1] octane framework to an isomeric bicyclo[3.2.1]octane skeleton via a bicyclo[2.2.2]octane derivative.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/37947/1/Synthesis_based_on_cyclohexadienes.pdf

Selvakumar, Natesan and Janaki, Seenivasaga N and Pramod, Kakumanu and Rao, Subba GSR (1995) Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels. In: Perkin Transactions 1 (7). pp. 839-846.

Publicador

Royal Society of Chemistry

Relação

http://pubs.rsc.org/en/Content/ArticleLanding/1995/P1/p19950000839

http://eprints.iisc.ernet.in/37947/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed