Perturbation of the infrared spectrum of lanthanum cobaltate induced by vibronic coupling


Autoria(s): Mortimer, R; Powell, JG; Vasanthacharya, NY
Data(s)

01/04/1995

Resumo

Anomalous changes in the infrared intensity of the cobalt-oxygen stretching modes in the infrared spectrum of lanthanum cobaltate (LaCoO3) suggest vibronic coupling. This phenomenon has been studied by infrared vibrational spectroscopy both by temperature-induced changes of spin-state occupation and pressure-induced changes of the crystal field splitting 10Dq.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/37856/1/Perturbation_of_the_Infrared.pdf

Mortimer, R and Powell, JG and Vasanthacharya, NY (1995) Perturbation of the infrared spectrum of lanthanum cobaltate induced by vibronic coupling. In: Synthetic Metals, 71 (1-3). pp. 2045-2046.

Publicador

Elsevier Science

Relação

http://dx.doi.org/10.1016/0379-6779(94)03158-3

http://eprints.iisc.ernet.in/37856/

Palavras-Chave #Solid State & Structural Chemistry Unit
Tipo

Journal Article

PeerReviewed