The generation of carbonyl compounds from acetals and ketals by iodotrichlorosilane (ITCS)
| Data(s) |
17/03/1992
|
|---|---|
| Resumo |
Cheap and readily available iodotrichlorosilane (SiCl4 / NaI) readily regenerates aldehydes and ketones from cyclic and acyclic acetals and ketals, in 20–60 min at ambient temperature. The reaction is highly chemoselective as phenolic ethers and esters are not cleaved. The pathway for the process is unlike any previously proposed. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/37771/1/THE_GENERATION_OF.pdf Elmorsy, Saad S and Bhatt, MV and Pelter, Andrew (1992) The generation of carbonyl compounds from acetals and ketals by iodotrichlorosilane (ITCS). In: Tetrahedron Letters, 33 (12). pp. 1657-1660. |
| Publicador |
Elsevier science |
| Relação |
http://dx.doi.org/10.1016/S0040-4039(00)91700-3 http://eprints.iisc.ernet.in/37771/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
