A total synthesis of 11-O-methyldebenzoyltashironin
| Data(s) |
13/04/2011
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| Resumo |
A concise total synthesis of 11-O-methyldebenzoyltashironin is reported in which oxidative dearomatization-IMDA-RCM triad constitutes the key ring forming steps, while an unorthodox DIBAL-H mediated stereo- and regioselective reductive epoxide openings and implementation of the vinyl bromide-carbonyl equivalency concept were pivotal to the success of this endeavor. (C) 2011 Elsevier Ltd. All rights reserved. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/37671/1/Total.pdf Mehta, Goverdhan and Maity, Pulakesh (2011) A total synthesis of 11-O-methyldebenzoyltashironin. In: Tetrahedron Letters, 52 (15). pp. 1749-1752. |
| Publicador |
Elsevier Science |
| Relação |
http://dx.doi.org/10.1016/j.tetlet.2011.02.012 http://eprints.iisc.ernet.in/37671/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
