Synthetic approaches to homogynolides A and B


Autoria(s): Srikrishna, Adusumili; Nagaraju, S; Reddy, TJ; Venkateswarlu, S
Data(s)

01/03/1996

Resumo

A four step, efficient and general methodology for the conversion of a cyclic ketone into the corresponding alpha-spiro-beta-methylene-gamma-butyrolactone, the key structural feature present in tricyclic sesquiterpenes bakkanes, has been developed employing a regiospecific 5-exo dig radical cyclisation reaction as the key step. The methodology has been extended to the total synthesis of bakkanes including homogynolide-B and chiral homogynolide-A.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/37622/1/Synthetic.pdf

Srikrishna, Adusumili and Nagaraju, S and Reddy, TJ and Venkateswarlu, S (1996) Synthetic approaches to homogynolides A and B. In: Pure and Applied Chemistry, 68 (3). pp. 699-702.

Publicador

International Union of Pure and Applied Chemistry

Relação

http://www.iupac.org/publications/pac/index.html

http://eprints.iisc.ernet.in/37622/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed