Synthetic approaches to homogynolides A and B
Data(s) |
01/03/1996
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Resumo |
A four step, efficient and general methodology for the conversion of a cyclic ketone into the corresponding alpha-spiro-beta-methylene-gamma-butyrolactone, the key structural feature present in tricyclic sesquiterpenes bakkanes, has been developed employing a regiospecific 5-exo dig radical cyclisation reaction as the key step. The methodology has been extended to the total synthesis of bakkanes including homogynolide-B and chiral homogynolide-A. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/37622/1/Synthetic.pdf Srikrishna, Adusumili and Nagaraju, S and Reddy, TJ and Venkateswarlu, S (1996) Synthetic approaches to homogynolides A and B. In: Pure and Applied Chemistry, 68 (3). pp. 699-702. |
Publicador |
International Union of Pure and Applied Chemistry |
Relação |
http://www.iupac.org/publications/pac/index.html http://eprints.iisc.ernet.in/37622/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |