Novel reduction (Zn-AcOH) of DDHQ esters - A new route to tropone synthesis


Autoria(s): Kasturi, Tirumalai R; Palle, Pragnacharyulu VP; Sattigeri, Jitendra A; Kumar, Kaipenchery A
Data(s)

29/01/1996

Resumo

Zn/acetic acid reaction of DDHQ esters 1 a-d gave the saturated acids 3 a-d and the hydrocarbons 7 a-d. The intermediacy of the aldehydes 10 and 11 in the formation of the products has been established. Oxidation of hydrocarbons 7a and 7b gave the corresponding tropones (5a and 5b).

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/37429/1/Novel_Reduction.pdf

Kasturi, Tirumalai R and Palle, Pragnacharyulu VP and Sattigeri, Jitendra A and Kumar, Kaipenchery A (1996) Novel reduction (Zn-AcOH) of DDHQ esters - A new route to tropone synthesis. In: Tetrahedron, 52 (5). pp. 1707-1712.

Publicador

Elsevier Science

Relação

http://dx.doi.org/10.1016/0040-4020(95)01006-8

http://eprints.iisc.ernet.in/37429/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed