Novel reduction (Zn-AcOH) of DDHQ esters - A new route to tropone synthesis
Data(s) |
29/01/1996
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Resumo |
Zn/acetic acid reaction of DDHQ esters 1 a-d gave the saturated acids 3 a-d and the hydrocarbons 7 a-d. The intermediacy of the aldehydes 10 and 11 in the formation of the products has been established. Oxidation of hydrocarbons 7a and 7b gave the corresponding tropones (5a and 5b). |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/37429/1/Novel_Reduction.pdf Kasturi, Tirumalai R and Palle, Pragnacharyulu VP and Sattigeri, Jitendra A and Kumar, Kaipenchery A (1996) Novel reduction (Zn-AcOH) of DDHQ esters - A new route to tropone synthesis. In: Tetrahedron, 52 (5). pp. 1707-1712. |
Publicador |
Elsevier Science |
Relação |
http://dx.doi.org/10.1016/0040-4020(95)01006-8 http://eprints.iisc.ernet.in/37429/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |