Mechanism of ?-cleavage in the excited states of keto sulfides
| Data(s) |
01/02/1992
|
|---|---|
| Resumo |
The beta-cleavage process in photoexcited ketones of structure RCOCH2X (X = CH2CH3, OCH3, SCH3; R = CH3, Ph) has been studied using the configuration interaction procedure within the framework of MINDO/3. The results explain qualitatively why the beta-cleavage process is faster than the alpha-cleavage process in keto sulfides while in keto ethers the reverse is true. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/37214/1/mech.pdf Raman, Sumathi and Asish K, Chandra (1992) Mechanism of ?-cleavage in the excited states of keto sulfides. In: Perkin Transactions 2 (2). pp. 291-294. |
| Publicador |
Royal Soc Chemistry |
| Relação |
http://pubs.rsc.org/en/content/articlelanding/1992/p2/p29920000291 http://eprints.iisc.ernet.in/37214/ |
| Palavras-Chave | #Inorganic & Physical Chemistry |
| Tipo |
Journal Article PeerReviewed |
