A simple strategy for spirocyclopentannullation of cyclic ketones. Formal total synthesis of (+/-)-acorone


Autoria(s): Srikrishna, Adusumili; Kumar, Praveen P; Viswajanani, Ranganathan
Data(s)

04/03/1996

Resumo

A general and simple methodology for spirocyclopentannulation of cyclic ketones (or 4,4-disubstituted cyclopentenones from acyclic ketones) and its application in the synthesis of the spirodienone 7 via a prochiral precursor constituting a formal total synthesis of (+/-)-acorone (6), are described.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/37038/1/A_Simple_Strategy_for.pdf

Srikrishna, Adusumili and Kumar, Praveen P and Viswajanani, Ranganathan (1996) A simple strategy for spirocyclopentannullation of cyclic ketones. Formal total synthesis of (+/-)-acorone. In: Tetrahedron Letters, 37 (10). pp. 1683-1686.

Publicador

Elsevier science

Relação

http://dx.doi.org/10.1016/0040-4039(96)00109-8

http://eprints.iisc.ernet.in/37038/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed