Asymmetric synthesis of steroidal Tröger's base analogues. X-Ray molecular structure of methyl 3?,12?-{6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-2,8-bisacetoxy}-5?-cholan-24-oate
| Data(s) |
21/08/1995
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|---|---|
| Resumo |
Cyclization of compound 5c in trifluoroacetic acid/hexamethylenetetramine produces Tröger's base analogue 6c in 75% yield with 70% diastereoselectivity. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/36937/1/steroida.pdf Uday, Maitra and Braja, Gopal Bag and Rao, Photon and Powell, Douglas (1995) Asymmetric synthesis of steroidal Tröger's base analogues. X-Ray molecular structure of methyl 3?,12?-{6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-2,8-bisacetoxy}-5?-cholan-24-oate. In: Perkin Transactions 1 (16). pp. 2049-2056. |
| Publicador |
Royal Society of Chemistry |
| Relação |
http://pubs.rsc.org/en/Content/ArticleLanding/1995/p1/P19950002049 http://eprints.iisc.ernet.in/36937/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
