Isomerisation of 1-methylene-2-methyl-2-(2-oxopropyl)-cyclohexanes to 2-methylene-1-methyl-1-(2-oxopropyl)-cyclohexanes by ene and retro-ene reaction
Data(s) |
18/07/1994
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Resumo |
Thermal activation of the normal Claisen products, the enones 4 7 and 14 in the presence of a catalytic amount of propionic acid generated the isomeric enones 6 9 and 15 via the sequential intramolecular ene-reaction of the enol tautomer followed by 1,5-hydrogen transfer (or retro ene-reaction) of the resultant acetyl cyclopropane intermediate. conversion of the enones 9 and 15 into the corresponding cyclohexenones 10 and 16 established the structures of the rearrangement products. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/36621/1/ISOMERIZATION.pdf Srikrishna, A and Venkateswarlu, A and Nagaraju, S and Krishnan, K (1994) Isomerisation of 1-methylene-2-methyl-2-(2-oxopropyl)-cyclohexanes to 2-methylene-1-methyl-1-(2-oxopropyl)-cyclohexanes by ene and retro-ene reaction. In: Tetrahedron, 50 (29). 8765 -8772 . |
Publicador |
Elsevier Science |
Relação |
http://dx.doi.org/10.1016/S0040-4020(01)85350-3 http://eprints.iisc.ernet.in/36621/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |