The Zintl ion As-7](2-): an example of an electron-deficient As-x radical anion
| Data(s) |
2011
|
|---|---|
| Resumo |
K(2,2,2-crypt)](2)As-7]center dot THF, 1 (2,2,2-crypt = 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo8.8.8]hexacosane) is the first well characterized seven-atom radical anion of group 15. UV-Vis spectroscopy confirms the presence and electronic structure of As-7](2-). Cyclic voltammetry in DMF solution shows the As-7(3) /As-7(2) redox couple as a one-electron reversible process. Theoretical investigations explore the bonding and properties of compound 1. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/36216/1/The_Zintl.pdf Mandal, Sukhendu and Liu, Ran and Reber, Arthur C and Qian, Meichun and Saavedra, Hector M and Ke, Xianglin and Schiffer, Peter and Sen, Saikat and Weiss, Paul S and Khanna, Shiv N and Sen, Ayusman (2011) The Zintl ion As-7](2-): an example of an electron-deficient As-x radical anion. In: Chemical Communications, 47 (11). pp. 3126-3128. |
| Publicador |
Royal Society of Chemistry |
| Relação |
http://pubs.rsc.org/en/Content/ArticleLanding/2011/CC/c0cc03219k http://eprints.iisc.ernet.in/36216/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
