Reaction of spironaphthalenones with hydroxylamine: Part I. A reinvestigation of the mechanism


Autoria(s): Kasturi, Tirumalai R; Jayaram, Srirangam K; Pragnacharyulu, Palle VP; Sattigeri, Jitendra A; Reddy, Gowravaram M; Kumar, Kaipenchery A
Data(s)

01/01/1993

Resumo

Spironaphthalenones 1b–g on reaction with hydroxylamine hydrochloride gave the expected pyrrolotropones 2b–g. Furanotropone 6, postulated as an intermediate in the formation of pyrrolotropones, remained unchanged on reaction with hydroxylamine hydrochloride in ethanol. Reaction of unsymmetrical spironaphthalenones 1h–o with NH2OH.HCl gave the rearranged pyrrolotropones 2h–o.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/35722/1/Reaction.pdf

Kasturi, Tirumalai R and Jayaram, Srirangam K and Pragnacharyulu, Palle VP and Sattigeri, Jitendra A and Reddy, Gowravaram M and Kumar, Kaipenchery A (1993) Reaction of spironaphthalenones with hydroxylamine: Part I. A reinvestigation of the mechanism. In: Tetrahedron, 49 (1). pp. 113-124.

Publicador

Elsevier Science

Relação

http://dx.doi.org/10.1016/S0040-4020(01)80511-1

http://eprints.iisc.ernet.in/35722/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed