Organometallic chemistry of diphosphazanes. Part 7. Platinum(II), palladium-(o), -(I) and -(II) complexes of RN[P(OPh)2]2(R = Me or Ph)


Autoria(s): Balakrishna, Maravanji S; Krishnamurthy, Setharampattu S; Murugavel, Ramaswamy; Nethaji, Munirathinam; Mathews, Irimpan I
Data(s)

07/02/1993

Resumo

The reactions of [MCl2(cod)](M = Pd or Pt, cod = cycloocta-1,5-diene) with RN[P(OPh)2]2[R = Me (L1) or Ph (L2)] afford the chelate complexes [MCl2L1] and [MCl2L2]. The dinuclear palladium(O) complex, [Pd2L13] has been synthesized by starting from [Pd2(dba)3](dba = dibenzylideneacetone). Redox condensation of [Pd2(dba)3] and [PdCl2(PhCN)2] in the presence of the diphosphazane ligands gives the dinuclear palladium(I) complexes [Pd2Cl2L12] and [Pd2Cl2L22]. The structures of the complexes have been deduced from 1H and 31P NMR spectroscopic data. Single-crystal X-ray diffraction studies confirm the structures of [Pd2L13] and [Pd2Cl2L22].

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/35656/1/Organo.pdf

Balakrishna, Maravanji S and Krishnamurthy, Setharampattu S and Murugavel, Ramaswamy and Nethaji, Munirathinam and Mathews, Irimpan I (1993) Organometallic chemistry of diphosphazanes. Part 7. Platinum(II), palladium-(o), -(I) and -(II) complexes of RN[P(OPh)2]2(R = Me or Ph). In: Dalton Transactions (3). pp. 477-482.

Publicador

Royal Society of Chemistry

Relação

http://pubs.rsc.org/en/Content/ArticleLanding/1993/DT/dt9930000477

http://eprints.iisc.ernet.in/35656/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed