Betwixt kinetic and thermodynamic control:'Pseudo-Thermodynamic control'


Autoria(s): Chandrasekhar, S
Data(s)

1993

Resumo

A third mechanistic category of organic reactions, conceptually in-between kinetic and thermodynamic control, needs to be recognized, in order to obtain a proper mechanistic description of certain highly important organic reactions, but also to avoid controversy. In fact, an instance of debatable conclusions having been reached is already known. The term �pseudo-thermodynamic control� is proposed for this newly-defined category, which would include any reaction in which intermediates along different routes mutually interconvert. The new category would thus encompass a very large number of reactions, many of them of great utility.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/35345/1/BETWIXT.pdf

Chandrasekhar, S (1993) Betwixt kinetic and thermodynamic control:'Pseudo-Thermodynamic control'. In: Research on Chemical Intermediates, 19 (5). pp. 443-448.

Publicador

Springer

Relação

http://www.springerlink.com/content/j970l37774551246/

http://eprints.iisc.ernet.in/35345/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed