Betwixt kinetic and thermodynamic control:'Pseudo-Thermodynamic control'
Data(s) |
1993
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Resumo |
A third mechanistic category of organic reactions, conceptually in-between kinetic and thermodynamic control, needs to be recognized, in order to obtain a proper mechanistic description of certain highly important organic reactions, but also to avoid controversy. In fact, an instance of debatable conclusions having been reached is already known. The term �pseudo-thermodynamic control� is proposed for this newly-defined category, which would include any reaction in which intermediates along different routes mutually interconvert. The new category would thus encompass a very large number of reactions, many of them of great utility. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/35345/1/BETWIXT.pdf Chandrasekhar, S (1993) Betwixt kinetic and thermodynamic control:'Pseudo-Thermodynamic control'. In: Research on Chemical Intermediates, 19 (5). pp. 443-448. |
Publicador |
Springer |
Relação |
http://www.springerlink.com/content/j970l37774551246/ http://eprints.iisc.ernet.in/35345/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |