A study of chemically prepared small metal clusters in the nonmetallic regime


Autoria(s): Kulkarni, Giridhar U; Aiyer, Hemantkumar N; Vijayakrishnan, Venugopal; Arunarkavalli, T; Rao, CNR
Data(s)

21/10/1993

Resumo

Small gold clusters [mean diameter (d)[less, similar] 1.4 nm], unlike larger clusters, show a higher Au(4f) binding energy relative to the bulk value and the presence of a conductance gap in tunnelling measurements, just as the molecular cluster compound, Au55(PPh3)12Cl6; small platinum clusters show similar nonmetallic features.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/35334/1/Study.pdf

Kulkarni, Giridhar U and Aiyer, Hemantkumar N and Vijayakrishnan, Venugopal and Arunarkavalli, T and Rao, CNR (1993) A study of chemically prepared small metal clusters in the nonmetallic regime. In: Journal of the Chemical Society - Series Chemical Communications (20). pp. 1545-1547.

Publicador

Royal Society of Chemistry

Relação

http://pubs.rsc.org/en/Content/ArticleLanding/1993/C3/C39930001545

http://eprints.iisc.ernet.in/35334/

Palavras-Chave #Materials Research Centre #Solid State & Structural Chemistry Unit
Tipo

Journal Article

PeerReviewed