An infrared spectroscopic study of the low-spin-high-spin transition in FexMn1-x(Phen)2(NCS)2: A composition-induced change in the order of the spin-state transition
Data(s) |
1990
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Resumo |
Infrared spectroscopy provides a valuable tool to investigate the spin-state transition in Fe(II) complexes of the type Fe(Phen)2(NCS)2. With progressive substitution of Fe by Mn, the first-order transition changes over to a second-order transition, with a high residual population of the high-spin state even at very low temperatures |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/34883/1/Spin.pdf Varma, Vijay and Fernandes, JR (1990) An infrared spectroscopic study of the low-spin-high-spin transition in FexMn1-x(Phen)2(NCS)2: A composition-induced change in the order of the spin-state transition. In: Chemical Physics Letters, 167 (4). pp. 367-370. |
Publicador |
Elsevier Science |
Relação |
http://dx.doi.org/10.1016/0009-2614(90)87184-S http://eprints.iisc.ernet.in/34883/ |
Palavras-Chave | #Solid State & Structural Chemistry Unit |
Tipo |
Journal Article PeerReviewed |