An Enantiospecific Approach to the 5-8-5 Tricyclic System of Basmanes
Data(s) |
01/12/2010
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Resumo |
An enantiospecific synthesis of the 5-8-5 tricyclic ring system present in the basmane diterpenes has been accomplished, starting from ethyl 3-isopropyl-2-methylene-1-methylcyclopentane-acetate readily available in five steps from (R)-limonene] employing an RCM reaction for the annulation of cyclooctane and an intramolecular rhodium carbenoid CH insertion reaction for the construction of the cyclopentane ring. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/34596/1/2010synlett3015_ASGNRGR.pdf Srikrishna, A and Nagaraju, Gopalasetty and Ravindra, G (2010) An Enantiospecific Approach to the 5-8-5 Tricyclic System of Basmanes. In: Synlett (20). pp. 3015-3018. |
Publicador |
Thieme Medical Publishers |
Relação |
https://www.thieme-connect.de/DOI/DOI?10.1055/s-0030-1259073 http://eprints.iisc.ernet.in/34596/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |