An Enantiospecific Approach to the 5-8-5 Tricyclic System of Basmanes


Autoria(s): Srikrishna, A; Nagaraju, Gopalasetty; Ravindra, G
Data(s)

01/12/2010

Resumo

An enantiospecific synthesis of the 5-8-5 tricyclic ring system present in the basmane diterpenes has been accomplished, starting from ethyl 3-isopropyl-2-methylene-1-methylcyclopentane-acetate readily available in five steps from (R)-limonene] employing an RCM reaction for the annulation of cyclooctane and an intramolecular rhodium carbenoid CH insertion reaction for the construction of the cyclopentane ring.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/34596/1/2010synlett3015_ASGNRGR.pdf

Srikrishna, A and Nagaraju, Gopalasetty and Ravindra, G (2010) An Enantiospecific Approach to the 5-8-5 Tricyclic System of Basmanes. In: Synlett (20). pp. 3015-3018.

Publicador

Thieme Medical Publishers

Relação

https://www.thieme-connect.de/DOI/DOI?10.1055/s-0030-1259073

http://eprints.iisc.ernet.in/34596/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed