Studies on ß-arylhydrazone-imine nickel(II) complexes—Examples of metal template syntheses


Autoria(s): Balakrishnan, KP; Krishnan, V
Data(s)

1979

Resumo

ß-arylhydrazone-imine ligand complexes of nickel(II), namely, 4,10-dimethyl-5,9-diazatrideca-4,9-diene-2,12-dione-3,11-diphenylhydrazonato nickel(II), Ni(acacpn)(N2Ph-R)2 and 1,11-diphenyl-3,9-dimethyl-4,8-diazaun-deca-3,8-diene,1,11-dione-2,10-diphenyl hydrazonato nickel(II), Ni (beacpn) (N2Ph-R)2, [R = H, o-CH3p-CH3] have been prepared by metal template reactions and characterized. Both the azomethine nitrogens and α-nitrogens of bis-hydrazone form the coordination sites of the square-planar geometry around the nickel(II) ion. Loss of CO from the molecule and subsequently an interesting methyl group migration to the nucleus of the chelate ring have been observed in the mass spectrum. Structures are proposed based on the spectral and magnetic properties.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/34533/1/STUDIES.pdf

Balakrishnan, KP and Krishnan, V (1979) Studies on ß-arylhydrazone-imine nickel(II) complexes—Examples of metal template syntheses. In: Journal of Inorganic and Nuclear Chemistry, 41 (1). pp. 37-40.

Publicador

Elsevier Science

Relação

http://dx.doi.org/10.1016/0022-1902(79)80389-9

http://eprints.iisc.ernet.in/34533/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed