Relation between effective atomic charge and chemical shifts in X-ray absorption spectra of transition-metal compounds


Autoria(s): Sarode, PR; Ramasesha, S; Madhusudan, WH; Rao, CNR
Data(s)

1979

Resumo

Chemical shifts of K absorption discontinuities, Delta E, of several manganese, iron and cobalt oxides with the metal in the formal oxidation states between +2 and +4, have been measured. These data, together with data in the literature on other compounds of these metals, can be fitted into the expression Delta E=aq+bq2, where q is the effective atomic charge on the metal. Theoretical considerations also support this functional relationship between Delta E and q.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/34109/1/Atomic.pdf

Sarode, PR and Ramasesha, S and Madhusudan, WH and Rao, CNR (1979) Relation between effective atomic charge and chemical shifts in X-ray absorption spectra of transition-metal compounds. In: Journal of Physics C: Solid State Physics, 12 (12). pp. 2439-2445.

Publicador

Institute of Physics

Relação

http://iopscience.iop.org/0022-3719/12/12/029

http://eprints.iisc.ernet.in/34109/

Palavras-Chave #Solid State & Structural Chemistry Unit
Tipo

Journal Article

PeerReviewed