Enantiospecific synthesis of tricyclo5.2.1.0(4,8)]decanes via acid catalysed rearrangement of isotwistanes


Autoria(s): Srikrishna, A; Satyanarayana, G; Kumar, Pramod
Data(s)

16/01/2006

Resumo

An acid catalysed rearrangement was employed for the enantiospecific conversion of isotwistanol to tricyclo5.2.1.0(4.8)]-decanes, which provided support for the proposed biosynthesis of allopupukeananes from pupukeananes. The strategy has been further extended to the enantiospecific synthesis of a homobrexane. (c) 2005 Elsevier Ltd. All rights reserved.

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application/pdf

Identificador

http://eprints.iisc.ernet.in/32872/1/sdarticle.pdf

Srikrishna, A and Satyanarayana, G and Kumar, Pramod (2006) Enantiospecific synthesis of tricyclo5.2.1.0(4,8)]decanes via acid catalysed rearrangement of isotwistanes. In: Tetrahedron Letters, 47 (3). pp. 363-366.

Publicador

Elsevier Science

Relação

http://dx.doi.org/10.1016/j.tetlet.2005.11.008

http://eprints.iisc.ernet.in/32872/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed