A bifunctional approach towards the mild oxidation of organic halides: 2-dimethylamino-N,N-dimethylaniline N-oxide


Autoria(s): Chandrasekhar, Sosale; Sridhar, Malayalam
Data(s)

08/07/2000

Resumo

The titled reagent incorporates an oxygen-centred nucleophile and a basic moiety�in a suitably mutual orientation�in the same molecule. It oxidises various primary benzylic bromides to the corresponding aromatic aldehydes under relatively mild conditions (MeCN/rt�50°C/6�24 h) in high yields (83�97%), and is thus a useful alternative to the Kornblum procedure.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/32538/1/mild.pdf

Chandrasekhar, Sosale and Sridhar, Malayalam (2000) A bifunctional approach towards the mild oxidation of organic halides: 2-dimethylamino-N,N-dimethylaniline N-oxide. In: Tetrahedron Letters, 41 (28). 5423-5425 .

Publicador

Elsevier Science

Relação

http://dx.doi.org/10.1016/S0040-4039(00)00874-1

http://eprints.iisc.ernet.in/32538/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed