A bifunctional approach towards the mild oxidation of organic halides: 2-dimethylamino-N,N-dimethylaniline N-oxide
Data(s) |
08/07/2000
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Resumo |
The titled reagent incorporates an oxygen-centred nucleophile and a basic moiety�in a suitably mutual orientation�in the same molecule. It oxidises various primary benzylic bromides to the corresponding aromatic aldehydes under relatively mild conditions (MeCN/rt�50°C/6�24 h) in high yields (83�97%), and is thus a useful alternative to the Kornblum procedure. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/32538/1/mild.pdf Chandrasekhar, Sosale and Sridhar, Malayalam (2000) A bifunctional approach towards the mild oxidation of organic halides: 2-dimethylamino-N,N-dimethylaniline N-oxide. In: Tetrahedron Letters, 41 (28). 5423-5425 . |
Publicador |
Elsevier Science |
Relação |
http://dx.doi.org/10.1016/S0040-4039(00)00874-1 http://eprints.iisc.ernet.in/32538/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |