Tetrathiomolybdate Mediated Rearrangement of Aziridinemethanol Tosylates: A Thia-Aza-Payne Rearrangement


Autoria(s): Sureshkumar, Devarajulu; Koutha, Srinivasamurthy; Ganesh, Venkataraman; Chandrasekaran, Srinivasan
Data(s)

20/08/2010

Resumo

Aziridinemethanol sulfonate esters react with tetrathiomolybdate 1 to give thiirane derivatives as the major product and cyclic disulfides as minor product under mild reaction conditions via an unprecedented thia-aza-Payne-type rearrangement. Interestingly, when the reaction of I was carried out with 2-aziridino-cyclohexanol derivatives it resulted in the formation of thia-bicyclo[3.1.1]heptane or dithia-bicyclo[3.2.1]octane derivatives.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/31977/1/aza.pdf

Sureshkumar, Devarajulu and Koutha, Srinivasamurthy and Ganesh, Venkataraman and Chandrasekaran, Srinivasan (2010) Tetrathiomolybdate Mediated Rearrangement of Aziridinemethanol Tosylates: A Thia-Aza-Payne Rearrangement. In: Journal of Organic Chemistry, 75 (16). pp. 5533-5541.

Publicador

American Chemical Society

Relação

http://pubs.acs.org/doi/abs/10.1021/jo100640w

http://eprints.iisc.ernet.in/31977/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed