pH mediated delamination of anionic clay-like nickel-zinc hydroxysalt in water through intercalation of zwitterionic p-aminobenzoate ions


Autoria(s): Britto, Sylvia; Rajamathi, JT; Ravishankar, N; Shivakumara, C; Rajamathi, M
Data(s)

01/02/2006

Resumo

p-aminobenzoate could be intercalated into the anionic clay, Ni3Zn2(OH)(8)(OAc)(2)center dot 2H(2)O at a high pH (similar to 10). When the pH was reduced to similar to 7 while washing colloidal dispersion due to delamination was observed. The development of partial positive charge on the amine end of the intercalated anion causes repulsion between the layers leading to delamination and colloidal dispersion of monolayers in water. The layers could be restacked from the colloid to form the parent solid either by increasing the pH or by evaporation.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/31786/1/d103373.pdf

Britto, Sylvia and Rajamathi, JT and Ravishankar, N and Shivakumara, C and Rajamathi, M (2006) pH mediated delamination of anionic clay-like nickel-zinc hydroxysalt in water through intercalation of zwitterionic p-aminobenzoate ions. In: Solid State Sciences, 8 (2). pp. 162-167.

Publicador

Elsevier Science

Relação

http://dx.doi.org/10.1016/j.solidstatesciences.2005.11.007

http://eprints.iisc.ernet.in/31786/

Palavras-Chave #Materials Research Centre #Solid State & Structural Chemistry Unit
Tipo

Journal Article

PeerReviewed