pH mediated delamination of anionic clay-like nickel-zinc hydroxysalt in water through intercalation of zwitterionic p-aminobenzoate ions
Data(s) |
01/02/2006
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Resumo |
p-aminobenzoate could be intercalated into the anionic clay, Ni3Zn2(OH)(8)(OAc)(2)center dot 2H(2)O at a high pH (similar to 10). When the pH was reduced to similar to 7 while washing colloidal dispersion due to delamination was observed. The development of partial positive charge on the amine end of the intercalated anion causes repulsion between the layers leading to delamination and colloidal dispersion of monolayers in water. The layers could be restacked from the colloid to form the parent solid either by increasing the pH or by evaporation. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/31786/1/d103373.pdf Britto, Sylvia and Rajamathi, JT and Ravishankar, N and Shivakumara, C and Rajamathi, M (2006) pH mediated delamination of anionic clay-like nickel-zinc hydroxysalt in water through intercalation of zwitterionic p-aminobenzoate ions. In: Solid State Sciences, 8 (2). pp. 162-167. |
Publicador |
Elsevier Science |
Relação |
http://dx.doi.org/10.1016/j.solidstatesciences.2005.11.007 http://eprints.iisc.ernet.in/31786/ |
Palavras-Chave | #Materials Research Centre #Solid State & Structural Chemistry Unit |
Tipo |
Journal Article PeerReviewed |