Total synthesis of (+/-)-herbertenediol
| Data(s) |
01/03/2006
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|---|---|
| Resumo |
A formal total synthesis of the sesquiterpene (+/-)-herbertenediol and its dimers mastigophorenes A-D has been accomplished, starting from vanillin via 2,3-dimethoxy-5-methylbenzaldehyde. A combination of Claisen rearrangement and ring-closing metathesis reactions were employed for the generation of the two vicinal quaternary carbons on a cyclopentane ring. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/31754/1/darticle.pdf Srikrishna, A and Satyanarayana, G (2006) Total synthesis of (+/-)-herbertenediol. In: Tetrahedron, 62 (12). pp. 2892-2900. |
| Publicador |
Elsevier Science |
| Relação |
http://dx.doi.org/10.1016/j.tet.2006.01.021 http://eprints.iisc.ernet.in/31754/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
