Improved procedures for the Beckmann rearrangement: the reaction of ketoxime carbonates with boron trifluoride etherate
| Data(s) |
08/07/2000
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|---|---|
| Resumo |
A variety of ketoxime ethyl carbonates-easily prepared from the oximes and ethyl chloroformate-undergo the Beckmann rearrangement upon treatment with 1 equivalent of boron trifluoride etherate, in dichloromethane solution at room temperature in excellent yields (generally 75-99%). (C) 2000 Elsevier Science Ltd. All rights reserved. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/31167/1/reasctin.pdf Anilkumar, R and Chandrasekhar, Sosale (2000) Improved procedures for the Beckmann rearrangement: the reaction of ketoxime carbonates with boron trifluoride etherate. In: Tetrahedron Letters, 41 (28). pp. 5427-5429. |
| Publicador |
Elsevier Science |
| Relação |
http://dx.doi.org/10.1016/S0040-4039(00)00875-3 http://eprints.iisc.ernet.in/31167/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
