An enantiospecific approach to thapsanes from R-carvone: synthesis of (−)-thaps-8-en-5-ol†
Data(s) |
19/08/2000
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Resumo |
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon atoms, is accomplished starting from R-carvone. An intramolecular alkylation and an intramolecular diazoketone cyclopropanation reaction were employed for the stereo- and regiospecific generation of three contiguous quaternary carbon atoms present in the thapsane framework. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/31130/1/ane.pdf Srikrishna, A and Anebouselvy, K and Reddy, Jagadeeshwar T (2000) An enantiospecific approach to thapsanes from R-carvone: synthesis of (−)-thaps-8-en-5-ol†. In: Tetrahedron Letters, 41 (34). pp. 6643-6647. |
Publicador |
Elsevier Science |
Relação |
http://dx.doi.org/10.1016/S0040-4039(00)01107-2 http://eprints.iisc.ernet.in/31130/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |