Observation of a large coupling of a bound dihydrogen ligand to phosphorus ligands in trans-[(dppe)(2)Ru(eta(2)-H-2) (PF(OMe)(2))][BF4](2) complex


Autoria(s): Nisha, Mathew; Balaji, Jagirdar R
Data(s)

2000

Resumo

A new dicationic dihydrogen complex of the type trans-[(dppe)(2)Ru(eta (2)-H-2)(PF(OMe)(2))]BF4](2) has been prepared and characterized. A large coupling of about 50 Hz between the H-2 and trans-phosphorus ligand in this complex has been observed.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/31058/1/large.pdf

Nisha, Mathew and Balaji, Jagirdar R (2000) Observation of a large coupling of a bound dihydrogen ligand to phosphorus ligands in trans-[(dppe)(2)Ru(eta(2)-H-2) (PF(OMe)(2))][BF4](2) complex. In: Inorganic Chemistry, 39 (23). pp. 5404-5406.

Publicador

American Chemical Society

Relação

http://pubs.acs.org/doi/abs/10.1021/ic000419q

http://eprints.iisc.ernet.in/31058/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed