Generation of Cationic Two-Coordinate Group-13 Ligand Systems by Spontaneous Halide Ejection: Remarkably Nucleophile-Resistant (Dimethylamino)borylene Complexes
| Data(s) |
07/04/2010
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| Resumo |
Spontaneous ejection of chloride from a three-coordinate boron Lewis acid can be effected by employing very electron rich metal substituents and leads to the formation of a sterically unprotected terminal (dimethylamino)borylene complex that has a short metal-boron bond and remarkable resistance to attack by nucleophilic and protic reagents. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/28931/1/Borly.pdf Addy, DA and Pierce, GA and Vidovic, D and Mallick, D and Jemmis, ED and Goicoechea, JM and Aldridge, S (2010) Generation of Cationic Two-Coordinate Group-13 Ligand Systems by Spontaneous Halide Ejection: Remarkably Nucleophile-Resistant (Dimethylamino)borylene Complexes. In: Journal of the American Chemical Society, 132 (13). pp. 4586-4588. |
| Publicador |
American Chemical Society |
| Relação |
http://pubs.acs.org/doi/abs/10.1021/ja101192e http://eprints.iisc.ernet.in/28931/ |
| Palavras-Chave | #Inorganic & Physical Chemistry |
| Tipo |
Journal Article PeerReviewed |
