Heterocyclic Steroids .7. Rearrangement Of 1-Diethylamino-5-(Met-Methoxyphenoxy)-Pent-2-Yne
| Data(s) |
1973
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|---|---|
| Resumo |
Thermal rearrangement of diethylamino5-(m methoxyphenoxy)-pent-2-yne (3) gives 1-(m-methexyphenoxy)-pent-3,4-diene (14) in about 8% yield. Hydration of the latter yields 1-(m-methoxyphenoxy)-pentan-4-one (6), which has been synthesised by an unambiguous route. A mechanism of formation of the allene (14) from the amine (3) has been suggested. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/28839/1/12sdarticle.pdf Kasturi, TR and Govindan, G and Damodaran, KM and Subrahma, G (1973) Heterocyclic Steroids .7. Rearrangement Of 1-Diethylamino-5-(Met-Methoxyphenoxy)-Pent-2-Yne. In: Tetrahedron, 29 (5). pp. 715-718. |
| Publicador |
Elsevier Science |
| Relação |
http://dx.doi.org/10.1016/0040-4020(73)80083-3 http://eprints.iisc.ernet.in/28839/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
