The emission spectrum of bismuth monofluoride BiF—‘A’ system


Autoria(s): Sankaranarayanan, S; Narayanan, PS; Patel, MM
Data(s)

01/06/1964

Resumo

The observation of (A-X) system of BiF has been extended up to λ 5316 and twenty new bands belonging to this system have been recorded. The band heads could be represented by the following equation: {Mathematical expression} Seven other faint bands in the region λ 5316-5492 have also been reported, which, however, could not be classified. By our analysis of the present data and from known thermochemical data it has been deduced that the ground state dissociation energy is, in all probability, around 20000 cm.-1 (∼2·5 ev.) and that the dissociation products are the normal Bi and F atoms. The dissociation energy of the upper state and the correlation rules have been used to show that the dissociation products in the upper state are very likely to be Bi atom in the excited state2D3/2 and F atom in its ground state (2P3/2).

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/28009/1/25.pdf

Sankaranarayanan, S and Narayanan, PS and Patel, MM (1964) The emission spectrum of bismuth monofluoride BiF—‘A’ system. In: Proceedings of the Indian Academy of Sciences - Section A, 59 (6). pp. 378-384.

Publicador

Indian Academy of Sciences

Relação

http://www.springerlink.com/content/g6l45r2g05j137uk/

http://eprints.iisc.ernet.in/28009/

Palavras-Chave #Physics
Tipo

Journal Article

PeerReviewed