Quinone studies—Istar, open: Evidence for a new type of substitution reaction of phenanthrene-9,10-quinone derivatives
Data(s) |
1964
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Resumo |
The para orientation by the carbonyl groups in the bromination of phenanthrenequinone derivatives has been explained on the basis of an excited state resulting from thermal excitation of the quinone and/or from a n→π* transition of the nonbonding electrons of the oxygen atoms. A general preparative method for the syntheses of 3-bromophenanthrenequinone derivatives has been developed. The structure of 2-nitro-6-bromophenanthrenequinone has been established by degradation. Synthesis of 2-nitro-6-bromofluorenone is described. Direct bromination of phenanthrenequinone to 2-bromo and 2,7-dibromo derivatives has also been described. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/27977/1/14.pdf Bhatt, MV (1964) Quinone studies—Istar, open: Evidence for a new type of substitution reaction of phenanthrene-9,10-quinone derivatives. In: Tetrahedron, 20 (4). pp. 803-821. |
Publicador |
Elsevier Science |
Relação |
http://dx.doi.org/10.1016/S0040-4020(01)98413-3 http://eprints.iisc.ernet.in/27977/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |