Dehydrogenation of Butyl Alcohol in Fixed Catalyst Beds
Data(s) |
1969
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Resumo |
The vapor-phase dehydrogenation of 1 -butanol to butyraldehyde was studied in a fixed bed of catalyst from 250° to 360° C. Of all the catalysts studied during preliminary investigation, the one containing 90% copper, 8% chromia, and 2% carbon supported on pumice was best, with high activity and selectivity. The data are expressed in the form of a first-order irreversible reaction rate equation. Single-site surface reaction (hydrogen adsorbed) is the rate-controlling mechanism at all the temperatures studied. The rate data obtained in the entire range of experimental conditions fit the rate equation based on this mechanism with a standard deviation of ± 22.8%. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/27593/1/8.pdf Rao, UR and Kumar, Rajinder and Kuloor, NR (1969) Dehydrogenation of Butyl Alcohol in Fixed Catalyst Beds. In: Iandec Process Design and Development, 8 (1). pp. 9-16. |
Publicador |
American Chemical Society |
Relação |
http://pubs.acs.org/doi/abs/10.1021/i260029a003 http://eprints.iisc.ernet.in/27593/ |
Palavras-Chave | #Chemical Engineering |
Tipo |
Journal Article PeerReviewed |