Ru(II)-CO complexes of thioarylazoimidazoles: Syntheses, structures, spectroscopy and DFT calculation
| Data(s) |
01/02/2010
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| Resumo |
The complexes, cis-(CO)-trans-(Cl)-[Ru(SRaaiNR)(CO)(2)Cl-2] (2) and trans-(Cl)-[Ru(SRaaiNR)(CO)Cl-2] (3) (SRaaiNR = 1-alkyl-2-{(o-thioalkyl)phenylazo}imidazoles; R = Me (1a) and Et (1b)) have been synthesized and characterized. The structural confirmation is achieved by single crystal X-ray structure determinations. The complexes show Ru(III)/Ru(II) couple and ligand reductions. Electronic structure and spectral properties of the complexes have been explained with the DFT and TDDFT calculation. (C) 2009 Elsevier B.V. All rights reserved. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/26241/1/817.pdf Mondal, TK and Raghavaiah, P and Patra, AK and Sinha, C (2010) Ru(II)-CO complexes of thioarylazoimidazoles: Syntheses, structures, spectroscopy and DFT calculation. In: Inorganic Chemistry Communications, 13 (2). pp. 273-277. |
| Publicador |
Elsevier Science. |
| Relação |
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6VM7-4XVRYVR-1&_user=512776&_coverDate=02%2F28%2F2010&_rdoc=16&_fmt=high&_orig=browse&_srch=doc-info%28%23toc%236143%232010%23999869997%231602144%23FLA%23display%23Volume%29&_cdi=6143&_sort=d&_doca http://eprints.iisc.ernet.in/26241/ |
| Palavras-Chave | #Others |
| Tipo |
Journal Article PeerReviewed |
