Chemoselective reduction of azides catalyzed by molybdenum xanthate by using phenylsilane as the hydride source
| Data(s) |
02/01/2010
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|---|---|
| Resumo |
A chemoselective, neutral, and efficient strategy for the reduction of azides to corresponding amines catalyzed by dioxobis(N,N,-diethyldithiocarbamato) molybdenum complex (1, MoO2[S2CNEt2](2)) in the presence of phenylsilane is discovered. This chemoselective reduction strategy tolerates a variety of reducible functional groups. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/25413/1/5.pdf Maddani, Mahagundappa R and Moorthy, Saravana K and Prabhu, Kandikere R (2010) Chemoselective reduction of azides catalyzed by molybdenum xanthate by using phenylsilane as the hydride source. In: Tetrahedron, 66 (1). pp. 329-333. |
| Publicador |
Elsevier science |
| Relação |
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6THR-4XJWD09-7&_user=512776&_rdoc=1&_fmt=&_orig=search&_sort=d&_docanchor=&view=c&_acct=C000025298&_version=1&_urlVersion=0&_userid=512776&md5=e285822709ac56bcc70b2c3288a37544 http://eprints.iisc.ernet.in/25413/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
