N. m. r. and infrared spectroscopic studies of hydrogen bonding in hindered alcohols. An instance of a true hydrogen bonded dimer in an alcohol


Autoria(s): Becker, Edwin D; Tucker, Edwin E; Rao, CNR
Data(s)

1977

Resumo

Hydrogen bonding in the highly hindered alcohol 2,4-dimethyl-3-ethyl-3-pentanol has been studied by proton n.m.r. and infrared spectroscopy. This alcohol associates to form a dimer but no higher hydrogen bonded species; hence the monomer–dimer equilibrium can be studied without interference from competing processes. Spectral and thermodynamic properties for the hydrogen bonding are reported.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/24629/1/6.pdf

Becker, Edwin D and Tucker, Edwin E and Rao, CNR (1977) N. m. r. and infrared spectroscopic studies of hydrogen bonding in hindered alcohols. An instance of a true hydrogen bonded dimer in an alcohol. In: Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 73 . pp. 438-442.

Publicador

Royal Society London

Relação

http://www.rsc.org/publishing/journals/F2/article.asp?doi=F29777300438

http://eprints.iisc.ernet.in/24629/

Palavras-Chave #Solid State & Structural Chemistry Unit
Tipo

Journal Article

PeerReviewed