Tributyltin chloride-sodium cyanoborohydride mediated tandem radical cyclisation-reductive demethoxylation sequence

Autoria(s): Srikrishna, A; Viswajanani, R; Yelamaggad, CV
Data(s)

28/07/1997
Resumo

Reaction of the bromoketals 3, 7a-g and 11 with tri-n-butyltin chloride and sodium cyanoborohydride in the presence of a catalytic amount of AIBN furnished the ethers 5, 8a-g and 13 via a tandem sequence comprising of a radical cyclisation reaction and tri-n-butylhalostannane and sodium cyanoborohydride mediated reductive demethoxylation of the resulting cyclic ketals.
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application/pdf
Identificador

http://eprints.iisc.ernet.in/24585/1/http___www.sciencedirect.com_science__ob%3DMImg%26_imagekey%3DB6THR-3SHJ6SB-1W-4%26_cdi%3D5289%26_user%3D512776%26_orig%3Dsearch%26_coverDate%3D07%252F28%252F1997%26_sk%3D999469969%26view%3Dc%26wchp%3DdGLbVlb-zSkzS%26md5%3D7842f1e8d4631dticle.pdf

Srikrishna, A and Viswajanani, R and Yelamaggad, CV (1997) Tributyltin chloride-sodium cyanoborohydride mediated tandem radical cyclisation-reductive demethoxylation sequence. In: Tetrahedron, 53 (30). 10479 -10488.
Publicador

Elsevier Science
Relação

http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6THR-3SHJ6SB-1W&_user=512776&_rdoc=1&_fmt=&_orig=search&_sort=d&_docanchor=&view=c&_acct=C000025298&_version=1&_urlVersion=0&_userid=512776&md5=0705c19778197d9442d609fc03fd7af1

http://eprints.iisc.ernet.in/24585/
Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed
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