Towards a temperature-guided molecular switch: an unusual reversible low-temperature polymorphic phase transition in a conformational locked environment
Data(s) |
2009
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Resumo |
A conformationally locked tetraacetate undergoes, quite akin to a temperature-guided molecular switch, a reversible thermal switching between two polymorphic modifications; the room-temperature alpha-form converted at -4 degrees C to a low-temperature denser beta-form, which displayed an unusual kinetic stability till 67 degrees C and transformed back to the alpha-form beyond this temperature. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/24551/1/fulltext.pdf Mehta, Goverdhan and Sen, Saikat (2009) Towards a temperature-guided molecular switch: an unusual reversible low-temperature polymorphic phase transition in a conformational locked environment. In: Chemical Communications (40). pp. 5981-5983. |
Publicador |
Royal Society of Chemistry |
Relação |
http://www.rsc.org/delivery/_ArticleLinking/ArticleLinking.asp?JournalCode=CC&Year=2009&ManuscriptID=b905651c&Iss=40 http://eprints.iisc.ernet.in/24551/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |