Coordination properties of vic-isonitrosoimines in their copper (II) and palladium (II) complexes
Data(s) |
1977
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Resumo |
Preparation and structural characterization of palladium (II) complexes of ligands III-V and copper (II) complexes of III are reported. The elemental analyses of the complexes show that the metal: ligand ratio is 1 : 2. The electrical conductance in acetone shows the non-electrolytic nature of the complexes. The diamagnetic character suggests a gross square-planar geometry for the palladium (II) complexes. Copper (II) complexes are paramagnetic with/~eff.~l'90 B.M. Spectral data suggest that in all the complexes the ligand coordinates to the metal (II) symmetrically through isonitroso-nitrogen and imine-nitrogen, forming a ¡ membered chelate ring. Amine-exchange reactions of the complexes are discussed and compared on the basis of their structures. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/24009/1/1.pdf Sudha, BP and Dixit, NS and Patel, CC (1977) Coordination properties of vic-isonitrosoimines in their copper (II) and palladium (II) complexes. In: Proceedings of the Indian Academy of Science Section A, 86 (5). pp. 471-477. |
Publicador |
Springer India, in co-publication with Indian Academy of Sciences |
Relação |
http://www.springerlink.com/content/7148863487743401/ http://eprints.iisc.ernet.in/24009/ |
Palavras-Chave | #Inorganic & Physical Chemistry |
Tipo |
Journal Article PeerReviewed |