Incomplete decomposition of alkali metal azides
Data(s) |
01/12/1976
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Resumo |
The thermal decomposition of sodium azide has been studied in the temperature range 240–360°C in vacuum and under pressure of an inert gas, argon. The results show that the decomposition is partial 360°C. From the observations made in the present work, namely: (i) the decomposition is incomplete both under vacuum and inert gas; (ii) mass spectrometric studies do not reveal any decrease in the intensity of the background species, CO+2, CO+, H2O+, and (iii) sodium metal remains in the ‘free state’ as seen by the formation of a metallic mirror at temperatures above 300°C, it has been argued that the partial nature of decompostion is due to the confinement of the decomposition to intermosaic regions within the lattice. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/23957/1/art2.pdf Mohan, V Krishna and Verneker, VR Pai (1976) Incomplete decomposition of alkali metal azides. In: Thermochimica Acta, 17 (3). pp. 343-349. |
Publicador |
Elsevier Science |
Relação |
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6THV-44J63G1-HW&_user=512776&_rdoc=1&_fmt=&_orig=search&_sort=d&_docanchor=&view=c&_acct=C000025298&_version=1&_urlVersion=0&_userid=512776&md5=35f246a1a3a2afeacccae00fdae240fc http://eprints.iisc.ernet.in/23957/ |
Palavras-Chave | #Inorganic & Physical Chemistry |
Tipo |
Journal Article PeerReviewed |