Thermal Decomposition of hydrazinium monoperchlorate in the solid state


Autoria(s): Verneker, VR Pai; Sharma, A Nagaraja; Jain, SR
Data(s)

01/12/1976

Resumo

Hydrazinium monoperchlorate (HP-1) has been shown to decompose thermally in the solid state according to the chemical equation: 5N2H5CIO4 = 4NH4CIO4+1HCI+3N2+4H2O The activation energy for the evolution of HCl as determined mass spectrometrically is 8.05 kcal mol−1 in the temperature range of 80 to 120°C. The rate of decomposition is seen to be altered by doping HP-1 with small concentrations of SO2−4, Ca2+ and Al3+.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/23955/1/article2.pdf

Verneker, VR Pai and Sharma, A Nagaraja and Jain, SR (1976) Thermal Decomposition of hydrazinium monoperchlorate in the solid state. In: Thermochimica Acta, 17 (3). pp. 319-323.

Publicador

Elsevier Science

Relação

http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6THV-44J63G1-HR&_user=512776&_rdoc=1&_fmt=&_orig=search&_sort=d&_docanchor=&view=c&_acct=C000025298&_version=1&_urlVersion=0&_userid=512776&md5=015dbc683be10d0f0dd94429ce2c7024

http://eprints.iisc.ernet.in/23955/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed