Ambidentate coordination of isonitrosoacetylacetone imines in their nickel(II) and palladium(II) complexes


Autoria(s): Bose, KS; Sharma, BC; Patel, CC
Data(s)

01/01/1973

Resumo

Nickel(I1) and palladium(I1) complexes of the types Ni(R-IAI)(IAI'), Pd(IAI)(IAI'), and Pd(R-IAI), , where IAI and IAI' represent isonitrosoacetylacetone imine and R-IAI represents its Aralkyl derivative, have been prepared. The molar conductance, molecular weight, magnetic moment, and ir, pmr, and electronic spectra of these com- plexes have been studied. It is suggested that the isonitroso group of R-IAI coordinates through the nitrogen and that of IAI' thiough the oxygen in Ni(R-IAI)(IAI'). In Pd(R-IAI), the isonitroso groups of both ligands coordinate through nitrogen while Pd(IAI)(IAI') has a structure similar to that of Ni(R-IAI)(IAI'). The amine- exchange reactions of nickel(I1) and palladium(I1) complexes are discussed and compared on the basis of their structures.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/23940/1/9.pdf

Bose, KS and Sharma, BC and Patel, CC (1973) Ambidentate coordination of isonitrosoacetylacetone imines in their nickel(II) and palladium(II) complexes. In: Inorganic Chemistry, 12 (1). pp. 120-123.

Publicador

American Chemical Society

Relação

http://pubs.acs.org/doi/abs/10.1021/ic50119a029

http://eprints.iisc.ernet.in/23940/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed