Heterocyclic steroidsâVII *1: Rearrangement of 1-diethylamino-5-(m-methoxyphenoxy)-pent-2-yne
| Data(s) |
1973
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|---|---|
| Resumo |
Thermal rearrangement of diethylamino 5-(m-methoxyphenoxy)-pent-2-yne (3) gives 1-(m-methexyphenoxy)-pent-3,4-diene (14) in about 8% yield. Hydration of the latter yields 1-(m-methoxyphenoxy)-pentan-4-one (6), which has been synthesised by an unambiguous route. A mechanism of formation of the allene (14) from the amine (3) has been suggested. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/23549/1/11.pdf Kasturi, TR and Govindan, G and Damodaran, KM and Subrahmanyam, G (1973) Heterocyclic steroidsâVII *1: Rearrangement of 1-diethylamino-5-(m-methoxyphenoxy)-pent-2-yne. In: Tetrahedron, 29 (5). pp. 715-718. |
| Publicador |
Elsevier Science |
| Relação |
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6THR-42JJVXR-7&_user=512776&_rdoc=1&_fmt=&_orig=search&_sort=d&_docanchor=&view=c&_acct=C000025298&_version=1&_urlVersion=0&_userid=512776&md5=1858999a7a6e55b125c6837b5259cfbd http://eprints.iisc.ernet.in/23549/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
