Charge distribution, dipole moments and molecular structure of some organogermanium compounds
Data(s) |
01/06/1974
|
---|---|
Resumo |
Formal charge distributions in, and the electric dipole moments of, a few simple organogermanium compounds have been evaluated by the method of R. P. Smith et al. [J. Amer. Chem. Soc., 73(1951) 2263]. The difference between the experimental and calculated moments in the case of alkylhalogermanes is explained in terms of the pπ—dπ back bonding effect outweighing the electron releasing effect. In unsaturated compounds, the differences are attributed to possible mesmeric effects involving the expansion of the germanium valence shell. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/23299/1/fulltextpdf.pdf Ramalingam, SK and Soundararajan, S (1974) Charge distribution, dipole moments and molecular structure of some organogermanium compounds. In: Journal of Organometallic Chemistry, 72 (1). pp. 59-63. |
Publicador |
Elsevier Science |
Relação |
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TGW-42VF6GG-3V&_user=512776&_rdoc=1&_fmt=&_orig=search&_sort=d&_docanchor=&view=c&_acct=C000025298&_version=1&_urlVersion=0&_userid=512776&md5=9cd2a9487ebf6c0fc8c01e6478ee04a9 http://eprints.iisc.ernet.in/23299/ |
Palavras-Chave | #Inorganic & Physical Chemistry |
Tipo |
Journal Article PeerReviewed |