Role of orbital symmetry in transition metal promoted ring opening reactions of methylenecyclopropanes and cyclobutenes
Data(s) |
01/05/1984
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Resumo |
Transition metals catalyse a variety of organic reactions, of which the ring opening of strained ring organic molecules generated a lot of interest. Theoreticians predicted a metal orbital catalysed pathway, which involved concerted bond breaking and bond forming. On the other hand experimentalists were able to show that the reaction was not proceeding through a concerted pathway by intercepting the intermediates involved. There remained, however, two ring systems methylenecyclopropanes and cyclobutenes—whose reactions with metal complexes seemed to be of a concerted nature. An analysis of the reactions of different metal complexes with these ring systems and the theoretical predictions provide a rationale for understanding these reactions. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/23236/1/c.pdf Samuelson, Ashoka G (1984) Role of orbital symmetry in transition metal promoted ring opening reactions of methylenecyclopropanes and cyclobutenes. In: Journal of chemical sciences, 93 (4). pp. 729-739. |
Publicador |
Indian academy of sciences |
Relação |
http://www.springerlink.com/content/q7h3122u021457x0/ http://eprints.iisc.ernet.in/23236/ |
Palavras-Chave | #Inorganic & Physical Chemistry |
Tipo |
Journal Article PeerReviewed |