Origin of the activation barrier in the process of hydrogen abstraction: the perturbation treatment


Autoria(s): Chandra, AK
Data(s)

1982

Resumo

The perturbation treatment previously given is extended to explain the process of hydrogen abstraction from the various hydrogen donor molecules by the triplet nπ* state of ketones or the ground state of the alkyl or alkoxy radical. The results suggest that, as the ionization energy of the donor bonds is decreased, the reaction is accelerated and it is not influenced by the bond strength of the donor bonds. The activation barrier in such reactions arises from a weakening of the charge resonance term as the ionization energy of the donor bond increases.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/23205/1/article.pdf

Chandra, AK (1982) Origin of the activation barrier in the process of hydrogen abstraction: the perturbation treatment. In: Journal of Photochemistry, 18 (2). pp. 151-159.

Publicador

Elsevier Science

Relação

http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6W96-44GHFJB-B7&_user=512776&_coverDate=12%2F31%2F1982&_rdoc=6&_fmt=high&_orig=browse&_srch=doc-info%28%23toc%236674%231982%23999819997%23274491%23FLP%23display%23Volume%29&_cdi=6674&_sort=d&_docan

http://eprints.iisc.ernet.in/23205/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed