Tautomeric forms of hydroxycyclotriphosphazatrienes; X-ray crystal structure of N3P3Ph2(OMe)3OH


Autoria(s): Dhathathreyan, KS; Krishnamurthy, SS; Murthy, AR Vasudeva; Cameron, T Stanley; Chan, Christine; Shaw, Robert A; Woods, Michael
Data(s)

1980

Resumo

The prefered tautomer(s) of hydroxycyclotriphosphazatrienes and prototropic exchange in solution have been established by 31P n.m.r. spectroscopy, thus confirming predictions deduced from basicity calculations; the X-ray structure of N3P3Ph2(OMe)3OH shows that it exists as the hydrogen-bonded dimer of the oxophosphazadiene tautomer in which a proton is adjacent to the PPh2 group.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/22923/1/fulltext.pdf

Dhathathreyan, KS and Krishnamurthy, SS and Murthy, AR Vasudeva and Cameron, T Stanley and Chan, Christine and Shaw, Robert A and Woods, Michael (1980) Tautomeric forms of hydroxycyclotriphosphazatrienes; X-ray crystal structure of N3P3Ph2(OMe)3OH. In: Journal of the Chemical Society, Chemical Communications . pp. 231-233.

Publicador

Royal Society of Chemistry

Relação

http://www.rsc.org/publishing/journals/C3/article.asp?doi=C39800000231

http://eprints.iisc.ernet.in/22923/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed